Information for A shape - dependent hydrophobic effect for tetrazoles in water
نویسندگان
چکیده
منابع مشابه
A shape-dependent hydrophobic effect for tetrazoles.
An adaptive tetrazole-derived host provides insight into tetrazolate-biomolecule interactions, and is the first member of a new family of receptors that function in pure water.
متن کاملSynthesis of Hydrophobic Silicalite Adsorbent from Domestic Resources: The Effect of Alkalinity on the Crystal Size and Morphology
A new polymorph crystalline silica composition having uniform pore dimensions were synthesized by calcining a crystalline hydrated alkyl-ammonium silicate. The pore dimensions approximately were 6 angstrom for silicalite-1 and 11 angstrom for silicalite-2 units. The silicalite-1 was prepared hydrothermally at a pH of about 10 from a reaction mixture consist of water, amorphous silica and a ...
متن کاملThe Impact of Wettability on Effective Properties of Cathode Catalyst Layer in a Proton Exchange Membrane Fuel Cell
The produced liquid water in cathode catalyst layer (CCL) has significant effect on the operation of proton exchange membrane fuel cell (PEMFC). To investigate this effect, the transport of oxygen in CCL in the presence of immiscible liquid water is studied applying a two-dimensional pore scale model. The CCL was reconstructed as an agglomerated system. To explore the wettability effects, diffe...
متن کاملMontmorillonite KSF as a very efficient heterogeneous catalyst for the synthesis of 5-substituted 1H-tetrazoles
Montmorillonite KSF has been used as an effective and non-toxic heterogeneous catalyst for one-pot synthesis of 5-substituted 1H-tetrazoles via [3+2] cycloaddition of sodium azide with a wide variety of nitriles. The reaction afforded high yields of the desired products in a short reaction time under mild reaction conditions. The catalyst can be recovered by simple filtration and reuse...
متن کاملIs it the shape of the cavity, or the shape of the water in the cavity?
Historical interpretations of the thermodynamics characterizing biomolecular recognition have marginalized the role of water. An important (even, perhaps, dominant) contribution to molecular recognition in water comes from the “hydrophobic effect,” in which non-polar portions of a ligand interact preferentially with non-polar regions of a protein. Water surrounds the ligand, and water fills the...
متن کامل